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VALTELINE; lordship of Austrian Italy, at the foot of the Alps, now forming the greater part of the province of Sondrio. It is bounded north by the Grisons, and was subject to these till 1797. Square miles, 1270; population, 81,000. This country, called by the Germans Veltlin, or Veltlein, and by the inhabitants Valle Tellina, is a valley, enclosed between two chains of lofty mountains, about fifty miles in length, and from eight to twenty in breadth. It is fruitful, and, throughout its whole extent, watered by the Adda. The whole country is divided into three districts, called Sopra, Mezzo and Sotto, or Upper, Middle and Lower. Tirano is the capital of the first, Sondrio of the second, and Morbegno of the last.

VALUE. The exchangeable value of commodities depends, at any given period, partly on the comparative facility of their production, and partly on the relation of the supply and demand. If any two or more commodities respectively required the same outlay of capital and labor to bring them to market, and if the supply of each were adjusted exactly according to the effectual demand; that is, were they all in sufficient abundance, and no more, to supply the wants of those able and willing to pay the outlay upon them, and the ordinary rate of profit at the time; they would each bring the same price, or be exchanged for the same quantity of any other commodity. But if any single commodity should happen to require less or more capital and labor for its production, while the quantity required to produce the others continued stationary, its value, as compared with them, would, in the first case, fall, and in the second, rise; and, supposing the cost of its production not to vary, its value might be increased by a falling off in the supply, or by an increase of demand, and conversely. But it is of importance to bear in mind, that all variations of price arising from any disproportion in the supply and demand of such commodities as may be freely produced in indefinite quantities, are temporary only; while those that are occasioned by changes in the cost of their production are permanent, at least as much so as the cause in which they originate. A general mourning occasions a transient rise in the price of black cloth; but, supposing that the fashion of wearing black were to continue, its price would not permanently vary; for those who previously manufactured blue and brown

cloths, &c., would henceforth manufacture only black cloth; and, the supply being in this way increased to the same extent as the demand, the price would settle at its old level. When the price of a freely produced commodity rises or falls, such variation may evidently be occasioned either by something affecting the commodity, or by something affecting the value of money. But when, instead of being confined to one, the generality of commodities rise or fall, the fair presumption is, that the change is not in them, but in the money with which they are compared. Exclusive, however, of the commodities now alluded to, there is a considerable class, whose producers or holders enjoy either an absolute or a partial monopoly of the supply. When such is the case, prices depend entirely or principally on the proportion between the supply and demand, and are not liable to be influenced, or only in a secondary degree, by changes in the cost of production. Antique statues and gems; the pictures of the great masters; wines of a peculiar flavor, produced in small quantities, in particular situations; and a few other articles, exist under what may be called absolute monopolies: their supply cannot be increased, and their price must, therefore, depend entirely on the competition of those who may wish to buy them, without being, in the slightest degree, influenced by the cost of their production. Monopolies are sometimes established by law; as when the power to supply the market with a particular article is made over to one individual, or society of individuals, without any limitation of the price at which it may be sold; which, of course, enables those possessed of the monopoly to exact the highest price for it that the competition of the buyers will afford, though such price may exceed the cost of production in any conceivable degree. The rights conveyed by patents sometimes establish a valuable monopoly; for they enable the inventors of improved methods of production to maintain, during the continuance of the patent, the price of the article at a level which may be much higher than is required to afford them the ordinary rate of profit. This advantage, however, by stimulating invention, and exciting to new discoveries, of which it is the natural and appropriate reward, instead of being injurious, is beneficial to the public. (See Patents.) There are also partial monopolies, depending upon situation, connexion, fashion, &c. These, and other inappreciable circumstances, sometimes occasion a difference

of thirty per cent. or more, in the price of the same article, in shops not very distant from each other. The effects on prices produced by the opening of new markets, or new sources of supply, and the effect of war in obstructing the ordinary channels of commercial intercourse, and occasioning extreme fluctuations in the supply and price of commodities, are well known. When a tax is laid on a commodity, its price necessarily rises in a corresponding proportion; for otherwise the producers would not obtain the ordinary rate of profit, and would, of course, withdraw from the business. Speculation has also a great influence on prices. It very rarely happens that either the actual supply of any species of produce in extensive demand, or the intensity of that demand, can be exactly measured. Every transaction in which an individual buys produce in order to sell it again, is, in fact, a speculation. The buyer anticipates that the demand for the article he has purchased will be such, at some future period, either more or less distant, that he will be able to dispose of it with a profit; and the success of the speculation depends, it is evident, on the skill with which he has estimated the circumstances that must determine the future price of the commodity. It follows, therefore, that in all highly commercial countries, where merchants are possessed of large capitals, and where they are left to be guided in the use of them by their own discretion and foresight, the prices of commodities will frequently be very much influenced, not merely by the actual occurrence of changes in the accustomed relation of the supply and demand, but by the anticipation of such changes. It is the business of the merchant to acquaint himself with every circumstance affecting the particular description of commodities in which he deals. He endeavors to obtain, by means of an extensive correspondence, the earliest and most authentic information with respect to every thing that may affect their supply or demand, or the cost of their production; and if he learned that the supply of an article has failed, or that, owing to changes of fashion, or to the opening of new channels of commerce, the demand for it has been increased, he would most likely be disposed to become a buyer, in anticipation of profiting by the rise of price, which, under the circumstances of the case, could hardly fail of taking place; or, if he were a holder of the article, he would refuse to part with it, unless for a higher price than

he would previously have accepted. If the intelligence received by the merchant had been of a contrary description; if, for example, he had learned that the article was now produced with greater facility, or that there was a falling off in the demand for it, caused by a change of fashion, or by the shutting up of some of the markets to which it had previously been admitted, he would have acted differently in this case, he would have anticipated a fall of prices, and would either have declined purchasing the article, except at a reduced rate, or have endeavored to get rid of it, supposing him to be a holder, by offering it at a lower price. In consequence of these operations, the prices of commodities, in different places and periods, are brought comparatively near to equality. All abrupt transitions from scarcity to abundance, and from abundance to scarcity, are avoided; an excess in one case is made to balance a deficiency in another, and the supply is distributed with a degree of steadiness and regularity that could hardly have been deemed attainable. The risk to which merchants are exposed, when they either sell off any commodity at a reduced price, in anticipation of a fall, or buy at an advanced price, in anticipation of a future rise, is a consequence principally of the extreme difficulty of ascertaining with accuracy the grounds on which an abundant or a deficient supply, or an increasing or decreasing demand, may be expected. Rules can here be of no service; every thing depends upon the talent, tact and knowledge of the party. Priority, but, above all, accuracy of intelligence, is, in such cases, of the utmost consequence. Without well authenticated data to go upon, every step taken may only lead to error. The instances, indeed, in which speculations, apparently contrived with the greatest judgment, have ended in bankruptcy and ruin, from a deficiency in this essential requisite, are so very numerous that every one must be acquainted with them. When a few leading merchants purchase in anticipation of an advance, or sell in anticipation of a fall, the speculation is often pushed beyond all reasonable limits, by the operations of those who are influenced by imitation only, and who have never, perhaps, reflected for a moment on the grounds on which a variation of price is anticipated. In speculation, as in most other things, one individual derives confidence from another. One purchases or sells, not because he has any really accurate in

formation as to the state of the demand and supply, but because some one else has done so before him. The original impulse is thus rapidly extended; and even those who are satisfied that a speculation, in anticipation of a rise of prices, is unsafe, and that there will be a recoil, not unfrequently adventure, in the expectation that they shall be able to withdraw before the recoil has begun. It may, we believe, speaking generally, be laid down as a sound practical rule, to avoid having any thing to do with a speculation in which many have already engaged. The competition of the speculators seldom fails speedily to render an adventure that might have been originally safe, extremely hazardous. If a commodity happen to be at an unusually reduced price in any particular market, it will rise the moment that different buyers appear in the field; and supposing, on the other hand, that it is bringing an unusually high price, it will fall, perhaps, far below the cost of production, as soon as supplies begin to be poured in by different merchants. Whatever, therefore, may be the success of those who originate a speculation, those who enter into it at an advanced period are almost sure to lose. To have been preceded by others ought not, in such matters, to inspire confidence on the contrary, it ought, unless there be something special in the case, to induce every considerate person to decline interfering with it. The maintenance of the freedom of intercourse between different countries, and the more general diffusion of sound instruction, seem to be the only means by which those miscalculations, that are often productive of great national as well as private loss, can be either obviated or mitigated. It is superfluous, perhaps, to observe that the precious metals are liable to all the variations of value already alJuded to. Not only, therefore, are prices, as was already remarked, affected by variations in the cost and supply of commodities, but also by changes in the cost and supply of gold and silver, whether arising from the exhaustion of old, or the discovery of new mines, improvements in the art of mining, changes of fashion, &c. Hence it is, that tables of the prices of commodities, extending for a considerable period, communicate far less solid information than is generally supposed, and, unless the necessary allowances be made, may lead to the most unfounded conclusions. The real value of any commodity depends on the quantity of labor required

for its production; but supposing that we were to set about inferring this real value, or the ultimate sacrifice required to obtain the commodity, from its price, it might happen (had the quantity of labor required for its production declined, but in a less degree than the quantity required to produce gold and silver), that its value would appear to rise when it had really diminished. When, however, the rate of wages, as well as the price of commodities, is given upon authentic data, a table of prices is valuable, inasmuch as it shows the extent of the command over the necessaries and conveniences of life, enjoyed by the bulk of the community, during the period through which it extends. Those desirous of detailed information as to the prices of commodities in Great Britain, in distant times, may consult the elaborate tables in the third volume of sir F. M. Eden's work On the Poor; and the fourth volume of Macpherson's Annals of Commerce. Arbuthnot's Tables of Ancient Coins, Weights, Measures, Prices, &c., are well known; but the statements are not much to be depended upon. The Traité de Métrologie of M. Paucton (4to., Paris, 1780) is the best work on this curious and difficult subject.

VAMPIRE. The vampire bat (vespertilio spectrum) is reddish-brown, and about the size of a magpie. It inhabits South America. It has been accused of destroying men and animals by sucking their blood. "But the truth," says Cuvier, in his Regne Animal," appears to be, that it inflicts only small wounds, which may probably become inflammatory and gangrenous from the influence of the climate." It is not altogether improbable that these animals gave origin to the fable of the harpies (q. v.); at least, some ancient authors make mention of these bats. Adelung believes the word vampire to be of Servian origin. The belief in bloodsucking spectres, also called vampires, is very old. The modern Greeks, according to Tournefort's Rélation d'un Voyage du Levant (1st vol., p. 52), call such monsters broucolacas; but even the ancient Greeks had their novσa; and the lamia and lemures of the Romans originated from the same superstition. In 1732, great commotions were caused in Hungary, and particularly in Servia, by the general belief in human vampires, so that investigations were instituted by the government. The common people believed that the bodies of persons who died under sentence of excommunication for sorcery or other crimes, did not decay, but devoured their

own flesh, and, during the night, left their graves, and sucked the blood of persons with whom they had been connected, so as to kill them.

VAN; a Dutch preposition. (See Von.) VAN DER VELDE, Adrian, William, and Charles. (See Velde.)

VAN DIEMEN'S LAND. (See Diemen's
Land.)

VAN DYCK. (See page 509.)
VAN EYCK. (See Eyck.)

VAN SPEYK, John Charles Joseph, born in 1802 or 1803, in Amsterdam, lost his parents early, was educated in an orphan asylum, and learned a mechanic's trade, which he soon quitted to enter the navy. He distinguished himself in the battle at Palembang, and was made a lieutenant. Feb. 5, 1831, he was in command of a gun-boat at the siege of Antwerp. Being driven by the wind up to the city, he was attacked by the Belgians, notwithstanding an armistice then existed. Upon their coming on deck and insulting the Dutch flag, in spite of his repeated warning that he should blow them up, he went below, and was shortly after found, by one of the crew, in the attitude of prayer. He told the man that the crew must take care of themselves, and, after a brief space, fired a pistol into the powder magazine, containing about 1500 pounds of powder, and blew up the vessel. Four of the crew, consisting of thirty-one, were saved: all the rest, with the Belgians, about forty on board, perished. The king of the Netherlands ordered that there should be always a vessel in the Dutch navy bearing the name of Van Speyk.

VAN SWIETEN. (See Swieten, Van.) VANADIUM; the name of a newly-discovered metal. It was first found in a lead mine at Zimapan, in Mexico, in the year 1801, by Del Rio, who announced it as a new metal, under the name of ery thronium; but the same mineral having soon afterwards been examined by Collet Descotils, he asserted that erythronium was merely impure chromium. Del Rio himself adopted the opinion of the French chemist, and considered the mineral as a subchromate of lead. In the year 1830, Sefström discovered this substance in a Swedish iron, remarkable for its ductility, obtained from the iron mine of Jaberg, not far from Jönköping, in Sweden. He named it Vanadium, from Vanadis, a Scandinavian deity. The finery cinder of the cast iron of Jaberg contains more vanadium than the iron itself, and it exists in it in the condition of vanadic acid. To 43

VOL. XII,

obtain the metal, the following process is adopted :-The finery cinder is powdered, and mixed with nitre, and carbonate of sodą, in the proportions of one part of cinder, one of nitre, and two parts of carbonate: this mixture is strongly calcined for an hour. The soluble portion of the powdered mass is dissolved by boiling water: the solution is filtered, and the excess of alkali saturated with nitric acid, and afterwards precipitated with muriate of barytes, or acetate of lead. The precipitate is vanadate of barytes or lead, containing also some phosphate of barytes or lead, silex, zircon and alumine. While it is still moist, it is to be decomposed by concentrated sulphuric acid: the solution immediately becomes of a deepred color; and, after having digested the mixture for half an hour, alcohol is added to it, and it is again digested. Ether is then formed, and the vanadic acid is reduced to the state of salifiable oxide, the solution of which is blue; and, when it begins to assume a sirupy consistence, it is mixed, in a platina crucible, with a little fluoric acid, to get rid of the silex; the evaporation is continued over the naked fire, and the sulphuric acid is at last expelled at a red heat. The residue is impure vanadic acid. It is fused with nitre, added in small portions at a time. The vanadic acid combines with the potash, and expels the nitric acid; and nitre is added, until it is found, that, on cooling a small portion of the mass, it ceases to be red. The mass is afterwards dissolved in water, and, after filtration, the residue is slightly washed. A piece of sal-ammoniac, larger than can be dissolved by it, is to be put into the filtered liquid. As this salt dissolves, a white pulverulent precipitate is formed, which is vanadate of ammonia, insoluble in a saturated solution of sal-ammoniac. The vanadate of ammonia ought to be washed, first with a solution of sal-ammoniac, and afterwards, to remove the sal-ammoniac, with alcohol of 0.86. It is to be again dissolved in boiling water, mixed with a little ammonia, filtered, and left to crystallize. It is from this salt that vanadic acid and oxide are afterwards obtained, by heating it gently in open vessels to procure the former, and in close vessels to prepare the latter. In order to obtain the metal, pieces of vanadic acid, which have been previously fused, are to be mixed with pieces of potassium, of equal bulk, in a porcelain crucible; the covej is to be well fastened on, and the cruci. ble is to be heated with a spirit lau

The reduction occurs almost instantaneously, with a kind of detonation. The crucible, when cold, is to be put into water, to dissolve the potash, and the reduced vanadium is to be collected on a filter: it is obtained in the state of a black powder, which shines in the sun, and takes a grayish metallic lustre under the burnisher; but this is not the true aspect of the metal. Vanadium is white; and, when its surface is polished, it resembles silver considerably, or molybdenum, which, of all metals, it is most like. It is not ductile, and is easily reduced to a powder of an iron-gray color. It is a good conductor of electricity. The powder of vanadium takes fire at a heat below redness, burns without energy, and leaves a black unfused oxide. Vanadium dissolves readily in nitric acid, and in aqua regia: the solution has a fine blue color. The sulphuric, muriatic and fluoric acids do not attack it at all, even when they are concentrated and boiling. It is not oxidized by the alkaline hydrates, and it may be heated with them to redness without undergoing any alteration, if the air be excluded. The compounds of vanadium and oxygen are three in number:1. Suboxide of vanadium. It is obtained by reducing vanadic, by hydrogen gas, at a red heat, or by fusing vanadic acid in a cavity in charcoal. It has not hitherto been combined with other bodies, or with acids or bases. When heated in the air, it takes fire, and burns, leaving an unfused black residue. It is composed of 89.538 parts of metal, and 10.862 of oxygen.-2. Oxide of vanadium. It is obtained in a state of purity by mixing 9.5 parts of suboxide with 11.5 parts of vanadic acid, and heating the mixture to whiteness in an atmosphere of carbonic acid gas. It is not fusible at the temperature at which glass softens. It is insoluble in water; but if it remains long in it, the water gradually becomes green in consequence of increased oxidation. It dissolves slowly, but completely, in the acids: the solution is blue, and the oxide acts as a base; but it combines with bases, and forms salts, which may be called vanadites. It is composed of 81.056 vanadium, and 18.944 oxygen.-3. Vanadic acid is obtained by exposing vanadate of ammonia to a heat near redness, in an open platina crucible, and stirring it occasionally. The vanadate decomposes, becomes at first black, and afterwards, in proportion as it absorbs atmospheric oxygen, of a red-brown color, which, by cooling, becomes gradually pale, and finishes by turning to a rust color. It is tasteless and inodorous:

it reddens the color of moistened litmus paper. As soon as it is red hot, it fuses. In this state, it sustains a white heat without losing oxygen, if kept from contact with combustible bodies. When fused, it crystallizes on cooling, and then exhibits a phenomenon which merits observation. It solidifies at a heat which is invisible in day-light; but the moment that solidification commences, à luminous circle extends from the periphery to the centre, where, owing to latent heat, becoming free, the mass remains red hot as long as the crystallization continues. The acid contracts much on solidifying, and is readily detached from the crucible: it is then of a yellowish-red color, and formed entirely of a mass of interlaced crystals. It is not a conductor of electricity. It is sligh⚫y soluble in water, to which it imparts a bright yellow color. One thousand parts of boiling water scarcely dissolve one part of acid. The acid is deposited, on evaporation, in the form of red concentric rings. It is easily reduced to the state of an oxide, especially under the influence of an acid. Fused on charcoal by the blow-pipe, it leaves a coherent mass, of the color of plumbago, which is the suboxide: with the phosphate of ammonia and soda, it gives a fine green color to glass, which appears brown while it is hot: with borax, it also gives a green glass. In this reaction, vanadium resembles chromium; but the green color, produced by the former, may be changed to yellow by the oxidating flame, which does not happen with chromium. With carbonate of soda, it is not reduced to the metallic state. It is composed of 74.044 vanadium and 25.955 oxygen. The affinity of vanadium for sulphur is but weak at moderately high temperatures; nevertheless, there are several modes of obtaining sulphurets of vanadium. Hitherto, only two have been formed. The sulphuret consists of 68.02 vanadium and 31.97 sulphur. The supersulphuret is composed of 58.647 vanadium and 41.353 sulphur. When vanadium is heated to redness in an atmosphere of vaporized phosphorus, they do not combine; but when phosphate of vanadium is heated to whiteness in a charcoal crucible, it is reduced, and gives a porous, gray, unfused mass, which may be compressed, and has then the color and lustre of plumbago.-Alloys of vanadium. In experiments upon vanadium, the surface of platina crucibles is often alloyed with vanadium, which does not alter either the color or the metallic lustre of the platina; but when it is afterwards

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