NMR and Chemistry: An introduction to modern NMR spectroscopy, Fourth EditionCRC Press, 17 февр. 2000 г. - Всего страниц: 400 Keeping mathematics to a minimum, this book introduces nuclear properties, nuclear screening, chemical shift, spin-spin coupling, and relaxation. It is one of the few books that provides the student with the physical background to NMR spectroscopy from the point of view of the whole of the periodic table rather than concentrating on the narrow applications of 1H and 13C NMR spectroscopy. Aids to structure determination, such as decoupling, the nuclear Overhauser effect, INEPT, DEPT, and special editing, and two dimensional NMR spectroscopy are discussed in detail with examples, including the complete assignment of the 1H and 13C NMR spectra of D-amygdain. The authors examine the requirements of a modern spectrometer and the effects of pulses and discuss the effects of dynamic processes as a function of temperature or pressure on NMR spectra. The book concludes with chapters on some of the applications of NMR spectroscopy to medical and non-medical imaging techniques and solid state chemistry of both I = F1/2 and I > F1/2 nuclei. Examples and problems, mainly from the recent inorganic/organometallic chemistry literature support the text throughout. Brief answers to all the problems are provided in the text with full answers at the end of the book. |
Содержание
nuclear screening | 17 |
Internuclear spinspin coupling | 45 |
Nuclear magnetic relaxation | 101 |
The spectrometer | 129 |
Making the spins dance | 167 |
NMR spectra of exchanging and reacting systems | 189 |
Multiple resonance and onedimensional pulse sequences | 233 |
Twodimensional NMR spectroscopy | 273 |
Magnetic resonance imaging and biomedical NMR | 335 |
Highresolution solidstate NMR | 355 |
385 | |
Answers to Questions | 391 |
397 | |
Другие издания - Просмотреть все
NMR and Chemistry: An introduction to modern NMR spectroscopy, Fourth Edition J.W. Akitt,B. E. Mann Ограниченный просмотр - 2017 |
NMR and Chemistry: An introduction to modern NMR spectroscopy, Fourth Edition J.W. Akitt,B. E. Mann Ограниченный просмотр - 2017 |
NMR and Chemistry: An Introduction to Modern NMR Spectroscopy, Fourth Edition J. W. Akitt Недоступно для просмотра - 2017 |
Часто встречающиеся слова и выражения
13C NMR spectrum ¹H NMR spectrum ¹H/ppm Figure aluminium American Chemical Society angle applied axis B₁ B₂ bond broadening calculated carbon atoms carbonyl CDCl3 CH₂ Chem chemical shift coil complex components compounds correlation coupling constant detected double irradiation doublet effect electron energy levels equation example exchange experiment field gradient give hydrogen increased intensity interaction isomers isotope ligand lines linewidth M₂ magnetic field methyl MHz 13C NMR MHz ¹H NMR molecule multiplet NMR signal NMR spectroscopy NMR spectrum normal nuclear nuclear Overhauser effect nuclei observed obtained output phase precession produces protons pulse sequence quadrupole ratio Reproduced with permission resonance result rotating frame sample screening shown in Fig shows signals due singlet solution solvent spec spectra spectrometer spin system spin-lattice relaxation spin-spin coupling structure T₁ T₂ technique temperature triplet trum two-dimensional values voxel xy plane zero
Ссылки на эту книгу
Physico-chemical Applications of NMR: A Practical Guide, Том 1 A. B. Kudryavtsev,W. Linert Ограниченный просмотр - 1996 |