Handbook of Grignard ReagentsCRC Press, 25 апр. 1996 г. - Всего страниц: 736 This handbook provides the theoretical and practical information necessary to explore new applications for Grignard reagents on a day-to-day basis, presenting a comprehensive overview of current research activities in Grignard chemistry. This book surveys specific reactions and applications of Grignard reagents, organized by type of substrate and t |
Содержание
1 Introduction | 1 |
2 Common Methods of Grignard Reagent Preparation | 9 |
3 Preparation of Grignard Reagents from Olefins and Acetylenes | 23 |
4 Magnesium Activation | 53 |
5 Safe Handling Practices of Industrial Scale Grignard Reagents | 79 |
6 Wet Analyses of Grignard Reagents | 89 |
7 Infrared and Raman Spectroscopy | 93 |
8 Nuclear Magnetic Resonance Analyses of Grignard Reagents | 103 |
19 Nucleophilic Addition to Conjugated CarbonCarbon Multiple Bonds | 381 |
O S N | 391 |
21 Nucleophilic Addition to Organometallic Vinylidene and Allyl Complexes | 397 |
22 The Barbier Reaction | 405 |
23 Grignard Reagents as Bases | 441 |
24 SN2 Versus SN2 | 455 |
Preparation and Reactions | 497 |
26 Formation and Reactions of Substituted 2Butene14diylmagnesium Complexes | 527 |
9 Crystal Structures of Grignard Reagents | 117 |
10 Mechanism of Grignard Reagent Formation | 145 |
11 Mechanisms of Reactions of Grignard Reagents | 219 |
12 StructureReactivity Relationships | 249 |
The Schlenk Equilibrium and Its Effect on Reactivity | 271 |
14 Effect of Trispyrazolylhydroborato Ligation | 291 |
15 Nucleophilic Substitution with Electrophilic Organic Main Group and Transition Metal Species | 307 |
16 Nucleophilic Addition to Unconjugated CC Multiple Bonds | 355 |
O S N P | 361 |
18 Nucleophilic Addition to MetalCarbon Multiple Bonds | 373 |
27 Spiroannulations Using Substituted 2Butene14diylmagnesium Complexes | 539 |
28 Asymmetric Synthesis Using Grignard Reagents | 557 |
29 MetalCatalyzed Reactions | 577 |
30 The Preparation of 11Bimetallics of Magnesium and Zinc | 633 |
31 Alkynyl Grignard Reagents and Their Uses | 645 |
32 Grignard Reagents and Silanes | 667 |
33 ZieglerNatta Catalysis | 677 |
34 Organomagnesium Compounds as Polymerization Initiators | 685 |
Back Cover | 703 |
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Часто встречающиеся слова и выражения
acetylenic acid addition reaction alcohol aldehydes alkyl allylic amines anion aryl Barbier Barbier reaction benzophenone benzyl Bickelhaupt bond Bull carbon carbonyl catalyst Chem chemical chemistry Chern Chim chiral chloride complex CuBr cyclic cyclopropyl derivatives di-Grignard reagent diethyl ether dimeric electrophiles enolate Entry esters ethylmagnesium bromide EtMgBr example formed Grignard reaction Grignard reagent Grignard reagent formation halides halogen intermediate iodide ketones leaving group ligand lithium magnesium surface mechanism methyl methylmagnesium Mg atom MgBr MgBr2 mixture molecules Normant nucleophilic nucleophilic substitution observed olefins optically active organic organomagnesium compounds Organomet Organometallics Ph Ph phenylmagnesium bromide PhMgBr Polym polymerization prepared presence propargyl R. D. Rieke radical ratio react reactions of Grignard reactivity reduction regioselectivity reported Rieke magnesium RMgX Scheme Schlenk equilibrium solution solvent species stereochemistry stereoselectivity steric studies substitution substrates synthesis Table temperature Tetrahedron Lett tetrahydrofuran toluene transition metal vinyl Walborsky yield