Handbook of Grignard ReagentsThis handbook provides the theoretical and practical information necessary to explore new applications for Grignard reagents on a day-to-day basis, presenting a comprehensive overview of current research activities in Grignard chemistry. This book surveys specific reactions and applications of Grignard reagents, organized by type of substrate and the general category of reaction. It also summarizes the spectrum of reactions exhibited by Grignard reagents. |
Contents
I | 3 |
III | 11 |
IV | 25 |
V | 55 |
VII | 81 |
VIII | 91 |
X | 95 |
XII | 105 |
XXXIII | 383 |
XXXV | 393 |
XXXVII | 399 |
XXXIX | 407 |
XLI | 443 |
XLIII | 457 |
XLV | 499 |
XLVII | 529 |
XIV | 119 |
XVI | 147 |
XVIII | 221 |
XIX | 251 |
XXI | 273 |
XXIII | 293 |
XXV | 309 |
XXVII | 357 |
XXIX | 363 |
XXXI | 375 |
XLIX | 541 |
LI | 559 |
LIII | 579 |
LV | 635 |
LVII | 647 |
LIX | 669 |
LXI | 679 |
LXIII | 687 |
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Common terms and phrases
acetylenic acid addition reaction alcohol alkyl allylic amines anion aryl Barbier reaction benzophenone benzyl Bickelhaupt bond Bull carbon carbonyl catalyst Chem chemical chemistry Chim chiral chloride complex CuBr cyclic cyclopropyl derivatives di-Grignard reagent diethyl ether dimeric electrophilic enolate Entry esters Et₂O ethylmagnesium bromide EtMgBr example formed Grignard reaction Grignard reagent Grignard reagent formation halides halogen intermediate iodide ketones leaving group ligand lithium magnesium surface mechanism methyl methylmagnesium MgBr MgBr2 MgCl mixture molecules monomers Normant nucleophilic nucleophilic addition observed olefins optically active organic organomagnesium compounds Organomet Organometallics Ph Ph phenylmagnesium bromide PhMgBr Polym polymerization prepared presence propargyl R. D. Rieke radical ratio react reactions of Grignard reactivity reduction regioselectivity reported Rieke magnesium RMgX Scheme Schlenk equilibrium solution solvent species stereochemistry stereoselectivity steric studies substitution substrates synthesis Table temperature Tetrahedron Lett tetrahydrofuran toluene transition metal vinyl Walborsky yield
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