Handbook of Grignard Reagents
This handbook provides the theoretical and practical information necessary to explore new applications for Grignard reagents on a day-to-day basis, presenting a comprehensive overview of current research activities in Grignard chemistry. This book surveys specific reactions and applications of Grignard reagents, organized by type of substrate and the general category of reaction. It also summarizes the spectrum of reactions exhibited by Grignard reagents.
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acetylenic acid active addition addition reaction afforded alcohol alkyl allylic amount anion aryl atom authors bond bromide Bull carbon carbonyl catalyst Chapter Chem chemical chemistry Chim chloride Commun complex compounds corresponding coupling cyclic cyclopropyl derivatives di-Grignard reagent diethyl ether dimeric discussed effect electron electrophilic Entry equilibrium example Figure followed formation formed give Grignard reaction Grignard reagent halides increase indicates initial intermediate involving isolated ketones lead ligand magnesium mechanism metal method methyl MgBr mixture nature nucleophilic observed obtained occur olefins optically organic organomagnesium Organomet Organometallics Polym polymerization prepared presence radical ratio react reaction reactivity recently reduction references relative reported Rieke RMgX Scheme selectivity showed shown similar solution solvent species step steric structure studies substitution substrates surface synthesis Table temperature Tetrahedron Lett transfer transition typically vinyl whereas yield
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